(2,3-Di-2-pyridylpyrazine-κ2 N 2,N 3)diiodidoplatinum(II)

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Tetra­chlorido(2,3-di-2-pyridylpyrazine-κ2 N 1,N 2)platinum(IV)

In the title complex, [PtCl(4)(C(14)H(10)N(4))], the Pt(IV) atom is six-coordinated in an octa-hedral configuration by two N atoms from one 2,3-di-2-pyridylpyrazine ligand and four terminal Cl atoms. Inter-molecular C-H⋯Cl and C-H⋯N hydrogen bonds stabilize the crystal structure.

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(Di-2-pyridyl­amine-κ2 N 2,N 2′)diiodidopalladium(II)

The Pd(II) ion in the title complex, [PdI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl-amine (dpa) ligand and two I(-) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 51.2 (2)°. In the crystal, pairs of complex mol-ecules are assembled through inter-mol...

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(Di-2-pyridyl­amine-κ2 N 2,N 2′)diiodidoplatinum(II)

The Pt(II) ion in the title complex, [PtI(2)(C(10)H(9)N(3))], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridyl-amine (dpa) ligand and by two I(-) anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex mol-ecules are assembled through inter-molecular N-H⋯I ...

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Dichlorido(di-2-pyridyl sulfide-κ2 N,N′)zinc(II)

The crystal structure of the title compound, [ZnCl(2)(C(10)H(8)N(2)S)], consists of a six-membered chelate ring in which the Zn atom is approximately tetra-hedrally coordinated by two chloride ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the ...

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cis-Dichloridobis(di-2-pyridyl­amine-κ2 N,N′)manganese(II)

In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa-hedral environment defined by four N atoms of two chelating di-2-pyridyl-amine (dpa) ligands and two Cl(-) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3 (2) and 30.9 (2)°. The complex mol-ecule...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812023501